Ignition and combustion of lunar propellants

The ignition and combustion of Al, Mg, and Al/Mg alloy particles in 99 percent O2/1 percent N2 mixtures is investigated at high temperatures and pressures for rocket engine applications. The 20 micron particles contain 0, 5, 10, 20, 40, 60, 80, and 100 weight percent Mg alloyed with Al, and are ignited in oxygen using the reflected shock in a shock tube near the endwall. Using this technique, the ignition delay and combustion times of the particles are measured at temperatures up to 3250 K as a function of Mg content for oxygen pressures of 8.5, 17, and 34 atm. An ignition model is developed which employs a simple lumped capacitance energy equation and temperature and pressure dependent particle and gas properties. Good agreement is achieved between the measured and predicted trends in the ignition delay times. For the particles investigated, the contribution of heterogeneous reaction to the heating of the particle is found to be significant at lower temperatures, but may be neglected as gas temperatures above 3000 K. As little as 10 percent Mg reduces the ignition delay time substantially at all pressures tested. The particle ignition delay times decrease with increasing Mg content, and this reduction becomes less pronounced as oxidizer temperature and pressure are increased

Barium Concentration in Rock Varnish: Implications for Calibrated Rock Varnish Dating Curves

Cation-ratio dating of rock varnish is a recently developed technique for obtaining surface exposure ages of a wide variety of geomorphic surfaces. As originally proposed, the technique utilizes a ratio among minor cations [(K+Ca)/Ti] in rock varnish. Although this varnish cation ratio is related to the Ti concentration, it can also be affected by the presence of Ba that may be partially included in the analyzed concentration of Ti. Barium is a minor constituent found in virtually all rock varnishes sampled from the Lake Mead area, Las Vegas Valley, and the Crater Flat region of southern Nevada. Barium is heterogeneously distributed in rock varnish, associated predominantly with Mn and secondarily with sulfur (detrital barite). Barium concentrations are apparently greater in varnishes found on young surfaces (\u3c 100 ka) than in varnishes found on older surfaces (\u3e 500 ka), and they are apparently greater in varnishes on low elevation surfaces than in varnishes on hill-slope or ridge deposits. In energy dispersive spectroscopy (EDS), Ba Lα and Lβ peaks overlap with Ti Kα and Kβ peaks. Unless decomposed , the overlapping peaks may yield erroneously large values for Ti. We have compared the effect of Ba concentration on calculated varnish cation ratios using: (I) quantitative EDS with the scanning electron microscope (SEM) that decomposes Ti and Ba peaks; (2) quantitative wavelength-dispersive spectroscopy (WDS) with an electron probe microanalyzer (EPM); (3) semiquantitative EDS with the SEM that decomposes Ti and Ba peaks; and (4) semi-quantitative EDS with the SEM that does not decompose Ti and Ba lines. Results suggest small amounts of Ba relative to Ti will not significantly change the value of the calculated varnish cation ratio with or without decomposition. However, if Ba concentrations are high relative to Ti, the effect on cation ratios is pronounced, resulting in anomalously low cation ratios. As younger varnishes and varnishes on topographically lower surfaces apparently have higher Ba concentrations, the effect of Ba on cation ratios calculated for younger rock varnishes and lower surfaces will be greater

Field trials of a methodology for locomotive brake testing to assess friction enhancement in the wheel/rail interface using a representative leaf layer

There are two options for testing the performance of rail vehicles and the application of material to the wheel/rail interface to influence friction, and therefore braking performance, in a low adhesion environment: laboratory work which is not representative of conditions in the field, and expensive track tests using fully instrumented modern vehicles largely using low adhesion simulants that are not representative of those that occur in the real world and usually applied over great lengths of track. This paper presents a third option: low-cost track tests. We determined the minimum of equipment and resources needed to produce low adhesion using a method more representative on Autumn conditions on rail and monitor the performance of rail vehicles when braking on it. This was mainly targeted at use for testing products applied to the wheel/rail interface to enhance traction, hence the need for real low adhesion causes. We present the methodology that we have developed, and some initial results showing that using it we can generate a low adhesion scenario when braking from 10 mph. This can be used to develop mitigation solutions for low adhesion in a more cost effective manner

Methodological Proposal of a 2Gen Approach to Treating Trauma for Mothers with Substance-Use and Their Children

Background: Existing literature shows adverse environments are detrimental to a family’s overall health and wellbeing. Estimates from 2016 indicate 18 million children experienced at least one family stressor such as economic hardship, exposure to parental substance use or witnessing domestic violence. Women are three times more likely to pass intergenerational trauma, or trauma passed from caregiver to child. If left untreated, adults and children are at risk for developing Posttraumatic Stress Disorder (PTSD) and rupturing the parent child relationship. Current services typically treat the parent and child individually, despite research showing positive relational and therapeutic effects when they are treated together . Treating parents and children at the same time bolsters attachment which strengthens the relationship between parent and child; however, there is currently no therapeutic framework in which both parents and children have equal importance in therapy . Objective: This study further develops the conceptual framework for a new “2Gen” intervention. Specifically, we specify a research design by which we plan to pilot this intervention. Method: A sample of 12 mothers and children residing in a substance abuse treatment facility will participate in 10 sessions of 2Gen. During simultaneous sessions, mothers will participate in group therapy to address post-traumatic stress (PTS) symptoms and substance use. They will also receive parent training designed to help enhance their parenting efficacy. Children will participate in group therapy in which they receive psychoeducation on trauma and learn coping skills. We plan to measure mother and child PTS symptoms, perceived stress, level of attachment and parental efficacy twice before the start of treatment and then again after treatment. We predict that mothers will report reductions in PTS, perceived stress and enhancements in mood, parenting confidence, and satisfaction in their relationship with their children. We anticipate that children will report decreased symptoms of PTS and perceived stress as well as increased satisfaction in the mother-child relationship and stability in overall mood. Implications: The goal of this study is to increase the trauma-focused treatment options available to both women and children who are struggling with intergenerational trauma due to the mother’s substance-use difficulties. Longer-term outcomes hope increase access to trauma mental health services for underprivileged families and motivate local agencies to adopt 2Gen programs to treat psychological outcomes associated with trauma. Future projects could be created to analyze the specific variables influencing outcomes of the 2Gen approach to treating trauma

Linear magnetoresistance due to multiple-electron scattering by low-mobility islands in an inhomogeneous conductor

Linear transverse magnetoresistance is commonly observed in many material systems including semimetals, narrow band-gap semiconductors, multi-layer graphene and topological insulators. It can originate in an inhomogeneous conductor from distortions in the current paths induced by macroscopic spatial fluctuations in the carrier mobility and it has been explained using a phenomenological semiclassical random resistor network model. However, the link between the linear magnetoresistance and the microscopic nature of the electron dynamics remains unknown. Here we demonstrate how the linear magnetoresistance arises from the stochastic behaviour of the electronic cycloidal trajectories around low-mobility islands in high-mobility inhomogeneous conductors and that this process is only weakly affected by the applied electric field strength. Also, we establish a quantitative link between the island morphology and the strength of linear magnetoresistance of relevance for future applications

Geospatial analysis and living urban geometry

This essay outlines how to incorporate morphological rules within the exigencies of our technological age. We propose using the current evolution of GIS (Geographical Information Systems) technologies beyond their original representational domain, towards predictive and dynamic spatial models that help in constructing the new discipline of "urban seeding". We condemn the high-rise tower block as an unsuitable typology for a living city, and propose to re-establish human-scale urban fabric that resembles the traditional city. Pedestrian presence, density, and movement all reveal that open space between modernist buildings is not urban at all, but neither is the open space found in today's sprawling suburbs. True urban space contains and encourages pedestrian interactions, and has to be designed and built according to specific rules. The opposition between traditional self-organized versus modernist planned cities challenges the very core of the urban planning discipline. Planning has to be re-framed from being a tool creating a fixed future to become a visionary adaptive tool of dynamic states in evolution

Anxiogenic CO2 Stimulus Elicits Exacerbated Hot Flash-like Responses in a Rat Menopause Model and Hot Flashes in Menopausal Women

Objective Since longitudinal studies determined that anxiety is a strong risk factor for hot flashes, we hypothesized that an anxiogenic stimulus that signals air hunger (hypercapnic, normoxic gas) would trigger an exacerbated hot flash-associated increase in tail skin temperature (TST) in a rat ovariectomy (OVEX) model of surgical menopause and hot flashes in symptomatic menopausal women. We also assessed TST responses in OVEX serotonin transporter (SERT)+/− rats that models a common polymorphism that is associated with increased climacteric symptoms in menopausal women and increases in anxiety traits. Methods OVEX and sham-OVEX rats (initial experiment) and wildtype and SERT+/− OVEX rats (subsequent experiment) were exposed to a 5 min infusion of 20%CO2 normoxic gas while measuring TST. Menopausal women were given brief 20% and 35%CO2 challenges, and hot flashes were self-reported and objectively verified. Results Compared to controls, OVEX rats had exacerbated increases in TST, and SERT+/− OVEX rats had prolonged TST increases following CO2. Most women reported mild/moderate hot flashes after CO2 challenges, and the hot flash severity to CO2 was positively correlated with daily hot flash frequency. Conclusions The studies demonstrate that this anxiogenic stimulus is capable of inducing cutaneous vasomotor responses in OVEX rats, and eliciting hot flashes in menopausal women. In rats, the severity of the response was mediated by loss of ovarian function and increased anxiety traits (SERT+/−), and, in women, by daily hot flash frequency. These findings may provide insights into anxiety related triggers and genetic risk factors for hot flashes in thermoneutral environments